Not VW, but basic idea of what you will need to do:
How To Align A Fender
here is a description of bumper alignment:
VWvortex Forums: just posting for the diy post
There should be "play" in all bolt locations (bolt size is smaller than the aread that it goes through for fender and hood hinges, by loosening the bolts and shimmy the panels around until it fits right, use universal sized(nonpaint damanging) shims to make all gaps correct.
could be that your bumper is causeing all issues and it just needs to be reinstalled, can't really tell from the pics which is off, but i would try to take the bumper cover/grille off and reinstall it first if your hood/fender and door/fender gaps are all uniform and good.
Gl!